For Hibernate 5.X just add
<dependency>
<groupId>org.hibernate</groupId>
<artifactId>hibernate-java8</artifactId>
<version>${hibernate.version}</version>
</dependency>
and
@NotNull
@Column(name = "date_time", nullable = false)
protected LocalDateTime dateTime;
will work without any additional effort.
See https://hibernate.atlassian.net/browse/HHH-8844
UPDATE:
Please have a look at Jeff Morin comment: since Hibernate 5.2.x it is enough
<dependency>
<groupId>org.hibernate</groupId>
<artifactId>hibernate-core</artifactId>
<version>5.2.1.Final</version>
</dependency>
<dependency>
<groupId>org.springframework</groupId>
<artifactId>spring-...</artifactId>
<version>4.3.1.RELEASE</version>
</dependency>
See https://github.com/hibernate/hibernate-orm/wiki/Migration-Guide—5.2 and
Integrate Hibernate 5.2 with Spring framework 4.x