Explode the Array of Struct in Hive

You need to explode only once (in conjunction with LATERAL VIEW). After exploding you can use a new column (called prod_and_ts in my example) which will be of struct type. Then, you can resolve the product_id and timestamps members of this new struct column to retrieve the desired result.

SELECT
   user_id,
   prod_and_ts.product_id as product_id,
   prod_and_ts.timestamps as timestamps
FROM 
   SampleTable 
   LATERAL VIEW explode(new_item) exploded_table as prod_and_ts;