There are historical reasons, mainly to make ASCII codes easy to convert:
Digits (0x30 to 0x39) have the binary prefix 110000:
0 is 110000
1 is 110001
2 is 110010
etc.
So if you wipe out the prefix (the first two ‘1’s), you end up with the digit in binary coded decimal.
Capital letters have the binary prefix 1000000:
A is 1000001
B is 1000010
C is 1000011
etc.
Same thing, if you remove the prefix (the first ‘1’), you end up with alphabet-indexed characters (A is 1, Z is 26, etc).
Lowercase letters have the binary prefix 1100000:
a is 1100001
b is 1100010
c is 1100011
etc.
Same as above. So if you add 32 (100000) to a capital letter, you have the lowercase version.